The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Peroxy radicals / Acylperoxy / CH3C(O)O2 / Tyndall(2001)_298K_195-290nm(eval)

DATAFILE: CH3C(O)O2_Tyndall(2001)_298K_195-290nm(eval).txt
NAME: acetylperoxy radical
FORMULA: CH3C(O)O2
AUTHOR(YEAR): Tyndall(2001)
T: 298K
λ: 195-290nm(eval)
BIBLIOGRAPHY: G.S. Tyndall, R.A. Cox, C. Granier, R. Lesclaux, G.K. Moortgat, M.J. Pilling, A.R. Ravishankara, and T.J. Wallington, "The atmospheric chemistry of small organic peroxy radicals", J. Geophys. Res. 106(D11), 12157-12182 (2001); DOI: 10.1029/2000JD900746
COMMENTS: Recommendation based on the data of

C.M. Roehl, D. Bauer, and G.K. Moortgat, "Absorption spectrum and kinetics of the acetylperoxy radical," J. Phys. Chem. 100, 4038-4047 (1996) and

M.M. Maricq and J.J. Szente, "The CH3C(O)O2 radical. Its UV spectrum, self-reaction kinetics, and reaction with CH3O2," J. Phys. Chem. 100, 4507-4513 (1996).

The data were fitted to the sum of two Gaussian functions:

σ = σmax1 × exp{-a1 [ln (ν - νmax1)]2} + σmax2 × exp{-a2 [ln (ν - νmax2)]2}

which yielded

σmax1 = 6.29×10-18cm2 molecule-1, λmax1 = 206.0 nm, and a1 = 168,
σmax2 = 3.26×10-18cm2 molecule-1, λmax2 = 246.1 nm, and a2 = 64.2

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