When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH3C(O)O2_Tyndall(2001)_298K_195-290nm(eval).txt |
NAME: | acetylperoxy radical |
FORMULA: | CH3C(O)O2 |
AUTHOR(YEAR): | Tyndall(2001) |
T: | 298K |
λ: | 195-290nm(eval) |
BIBLIOGRAPHY: |
G.S. Tyndall, R.A. Cox, C. Granier, R. Lesclaux, G.K. Moortgat, M.J. Pilling, A.R. Ravishankara, and T.J. Wallington, "The atmospheric chemistry of small organic peroxy radicals",
J. Geophys. Res. 106(D11), 12157-12182 (2001);
DOI: 10.1029/2000JD900746
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COMMENTS: | Recommendation based on the data of C.M. Roehl, D. Bauer, and G.K. Moortgat, "Absorption spectrum and kinetics of the acetylperoxy radical," J. Phys. Chem. 100, 4038-4047 (1996) and M.M. Maricq and J.J. Szente, "The CH3C(O)O2 radical. Its UV spectrum, self-reaction kinetics, and reaction with CH3O2," J. Phys. Chem. 100, 4507-4513 (1996). The data were fitted to the sum of two Gaussian functions: σ = σmax1 × exp{-a1 [ln (ν - νmax1)]2} + σmax2 × exp{-a2 [ln (ν - νmax2)]2} which yielded σmax1 = 6.29×10-18cm2 molecule-1, λmax1 = 206.0 nm, and a1 = 168, σmax2 = 3.26×10-18cm2 molecule-1, λmax2 = 246.1 nm, and a2 = 64.2 |
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